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Wilton has a wide variety of silicone molds.
They are Fondant and Gum Paste Molds and so they are food safe.
I am happy to announce, yes you can bake polymer clay in them. I tested at 275° and the clay popped right out afterwards. The mold didn't discolor although this is just one baking. There doesn't seem to be any degradation of the silicone mold. I would feel safe baking in them on a regular basis.